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3 Atomic spectra & energy levels

Electrons occupy discrete energy levels. A photon is emitted (or absorbed) when an electron drops (or jumps) between levels, with energy exactly equal to the gap. Transition energy ΔE = E<sub>high</sub> − E<sub>low</sub> = h f Gives a line spectrum: specific wavelengths only.

Emission vs absorption

  • Emission: electron drops a level → photon emitted → bright line.
  • Absorption: photon absorbed → electron jumps up → dark line in a continuous spectrum.
  • Line spectra are a “fingerprint” unique to each element.

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