← Chemical reactivity

Reading an equilibrium concentration-time graph

A recurring graph-interpretation task, distinct from predicting a shift by name: explaining WHAT a graph shows about equilibrium, and how the system responds when it is disturbed mid-graph.

What to look for on the graph

  • FLAT/CONSTANT sections: all three concentration lines running horizontally (unchanging) indicate the system IS at equilibrium — forward and reverse rates are equal, so net concentrations do not change, even though both reactions continue.
  • A SUDDEN JUMP in one species' concentration (e.g. more reactant added) marks the point of disturbance — read the graph for exactly which species changed and by how much.
  • AFTER the disturbance, concentrations move again before flattening out at NEW, different equilibrium values — this second flat section is the NEW equilibrium position, reached via Le Chatelier's response to the disturbance.
  • The DIRECTION each line moves after the disturbance tells you which way the equilibrium shifted — reactant lines falling and product lines rising means the system shifted toward products (forward), and vice versa.
Worked example Explaining a graph after adding extra reactant mid-experiment A concentration-time graph for CO(g) + 2H₂(g) ⇌ CH₃OH(g) is flat, then extra CO is added, causing the CO line to jump up. Explain how the system responds to restore equilibrium, referring to the graph. BEFORE THE ADDITION: all three lines are flat, showing the forward and reverse reaction rates were equal — the system was at equilibrium. THE DISTURBANCE: adding CO increases [CO], shown as a sudden upward jump in the CO line on the graph. THE RESPONSE: Le Chatelier's principle predicts the system shifts to PARTIALLY OPPOSE the increase — the forward reaction rate temporarily exceeds the reverse rate, consuming some of the extra CO (and H₂) to produce more CH₃OH. THE NEW EQUILIBRIUM: the graph shows CO and H₂ concentrations falling somewhat from their new peak, and CH₃OH rising, before all three lines flatten again at a NEW equilibrium — with CO higher than before (since not ALL of the addition is consumed) but CH₃OH also higher than before. ✓ Reference the SPECIFIC graph features (flat sections, the jump, the direction of movement afterward) throughout — a purely theoretical Le Chatelier answer with no reference to what the graph actually shows misses the "refer to the graph" instruction. ✕

Explaining the shift without referencing what the graph actually shows

When a question explicitly says "refer to the graph in your answer", a theoretically correct Le Chatelier explanation that never mentions the flat sections, the jump, or the direction lines move afterward has not met the instruction — always describe the specific visual features supporting your explanation.
Graph featureWhat it shows
All lines flatSystem at equilibrium — forward rate = reverse rate
A sudden jump in one lineThe point of external disturbance
Lines moving after the jump, then flattening againThe system shifting to a NEW equilibrium

Practice for this standard covers the whole topic — flashcards and quiz.