← Chemical reactivity
Reading an equilibrium concentration-time graph
A recurring graph-interpretation task, distinct from predicting a shift by name: explaining WHAT a graph shows about equilibrium, and how the system responds when it is disturbed mid-graph.What to look for on the graph
- FLAT/CONSTANT sections: all three concentration lines running horizontally (unchanging) indicate the system IS at equilibrium — forward and reverse rates are equal, so net concentrations do not change, even though both reactions continue.
- A SUDDEN JUMP in one species' concentration (e.g. more reactant added) marks the point of disturbance — read the graph for exactly which species changed and by how much.
- AFTER the disturbance, concentrations move again before flattening out at NEW, different equilibrium values — this second flat section is the NEW equilibrium position, reached via Le Chatelier's response to the disturbance.
- The DIRECTION each line moves after the disturbance tells you which way the equilibrium shifted — reactant lines falling and product lines rising means the system shifted toward products (forward), and vice versa.
Explaining the shift without referencing what the graph actually shows
When a question explicitly says "refer to the graph in your answer", a theoretically correct Le Chatelier explanation that never mentions the flat sections, the jump, or the direction lines move afterward has not met the instruction — always describe the specific visual features supporting your explanation.| Graph feature | What it shows |
|---|---|
| All lines flat | System at equilibrium — forward rate = reverse rate |
| A sudden jump in one line | The point of external disturbance |
| Lines moving after the jump, then flattening again | The system shifting to a NEW equilibrium |
Practice for this standard covers the whole topic — flashcards and quiz.